Synthesis of green nanosorbent from bovine serum albumin and curcumin for magnetic solid phase extraction of pesticides from food samples

Abstract

For the first time, a magnetic carbon nanocomposite was synthesized using one-step hydrothermal procedure, employing bovine serum albumin, curcumin, and ferric ammonium citrate. Additionally, the application of this novel composite as an adsorbent for magnetic dispersive solid phase extraction of fungicides and pesticides from water and food samples is a unique aspect of this study. Under optimum conditions (salt concentration: 5.0% w/v, pH: 7.0, desorption solvent: ethanol, sorbent amount: 20 mg, extraction time: 20 min, desorption time: 3 min, stirring rate: 500 rpm, sample volume: 30 mL, extraction temperature: room temperature, and desorption solvent volume: 150 μL) linearity (2.5 to 1400 ng mL⁻¹), coefficients of determination (R² ≥ 0.997), limits of detection (0.75 to 1.5 ng mL⁻¹), and limits of quantification (2.5 to 5.0 ng mL⁻¹) were achieved. The method validation results showed extraction recovery ranging from 71.2% to 93.4%, and preconcentration factors ranging from 142.5 to 186.1.