Plasma-Liquid Synthesis as a New Method for the Production of MXenes

IF 2.6 3区 物理与天体物理 Q3 ENGINEERING, CHEMICAL
Nikolay Sirotkin, Anna Khlyustova, Alexander Agafonov
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Abstract

In this work, the successful synthesis of nanostructures based on MXenes by initiating a pulse discharge between titanium wires immersed in carbon tetrachloride is presented. By choosing carbon tetrachloride as the environment, the formation of oxide structures in the synthesized samples could be avoided. The characterization of the obtained structures was carried out using various techniques, including scanning electron microscopy, X-ray phase analysis, EDS, Raman and FTIR spectroscopy. The results confirmed the successful formation of MXenes with a Cl occupying the interlayer space. The properties of the discharge initiated in CCl4 were also determined. The results suggest the potential of this plasma-liquid method for the synthesis of high-purity MXenes without impurities commonly found in conventionally prepared samples.

Abstract Image

等离子体-液体合成法作为生产 MXenes 的新方法
在这项研究中,通过在浸入四氯化碳的钛丝之间启动脉冲放电,成功合成了基于 MXenes 的纳米结构。通过选择四氯化碳作为环境,可以避免在合成样品中形成氧化物结构。利用各种技术,包括扫描电子显微镜、X 射线相分析、EDS、拉曼光谱和傅立叶变换红外光谱,对获得的结构进行了表征。结果证实成功形成了层间有 Cl- 存在的 MXenes。此外,还测定了在 CCl4 中放电的特性。结果表明,这种等离子体-液体方法具有合成高纯度 MXenes 的潜力,而且不含传统制备样品中常见的杂质。
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来源期刊
Plasma Chemistry and Plasma Processing
Plasma Chemistry and Plasma Processing 工程技术-工程:化工
CiteScore
5.90
自引率
8.30%
发文量
73
审稿时长
6-12 weeks
期刊介绍: Publishing original papers on fundamental and applied research in plasma chemistry and plasma processing, the scope of this journal includes processing plasmas ranging from non-thermal plasmas to thermal plasmas, and fundamental plasma studies as well as studies of specific plasma applications. Such applications include but are not limited to plasma catalysis, environmental processing including treatment of liquids and gases, biological applications of plasmas including plasma medicine and agriculture, surface modification and deposition, powder and nanostructure synthesis, energy applications including plasma combustion and reforming, resource recovery, coupling of plasmas and electrochemistry, and plasma etching. Studies of chemical kinetics in plasmas, and the interactions of plasmas with surfaces are also solicited. It is essential that submissions include substantial consideration of the role of the plasma, for example, the relevant plasma chemistry, plasma physics or plasma–surface interactions; manuscripts that consider solely the properties of materials or substances processed using a plasma are not within the journal’s scope.
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