1,4-Diazabicyclo[2.2.2]octane (DABCO) in Organic Synthesis and Catalysis: A Quinquennial Report (2019-to date)

IF 1.7 3区化学 Q3 CHEMISTRY, ORGANIC

Current Organic Chemistry Pub Date : 2024-06-12 DOI:10.2174/0113852728313865240528073519

Ravi Varala, Vittal Seema, Mohammed Mujahid Alam, Mohammed Amanullah, Beda Durga Prasad

引用次数: 0

Abstract

DABCO is one of the more effective basic organocatalysts/reagents that can be used for a range of organic transformations, including C-H functionalization, formation of hetero-hetero bonds, rearrangements, the synthesis of heterocyclic compounds, cyclizations and annulations, other miscellaneous reactions. This quinquennial review aims to critically and perceptively address noteworthy contributions of non chiral catalyst DABCO for regular organic transformations from 2019 onward. The key areas of attention were the advantages and limits of the approach, in addition to the mechanistic pathway, which is required for a specific organic transformation to be performed effectively.

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有机合成和催化中的 1,4-二氮杂双环[2.2.2]辛烷 (DABCO)：五年期报告（2019 年至今）

DABCO 是较为有效的基本有机催化剂/试剂之一，可用于一系列有机转化，包括 C-H 功能化、杂-杂键的形成、重排、杂环化合物的合成、环化和环化以及其他杂项反应。这篇五年一度的综述旨在批判性地、敏锐地探讨非手性催化剂DABCO自2019年以来在常规有机转化中做出的值得注意的贡献。重点关注的领域包括该方法的优势和局限，以及有效进行特定有机转化所需的机理途径。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Current Organic Chemistry 化学-有机化学

CiteScore

3.70

自引率

7.70%

发文量

审稿时长

1 months

期刊介绍： Current Organic Chemistry aims to provide in-depth/mini reviews on the current progress in various fields related to organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic and green chemistry, suitable aspects of medicinal chemistry and polymer chemistry, as well as analytical methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by chosen experts who are internationally known for their eminent research contributions. The Journal also accepts high quality research papers focusing on hot topics, highlights and letters besides thematic issues in these fields. Current Organic Chemistry should prove to be of great interest to organic chemists in academia and industry, who wish to keep abreast with recent developments in key fields of organic chemistry.

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