Dr. Pascal Telaar, Patrick Diehl, Prof. Dr. Martin Muhler
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引用次数: 0
Abstract
Industrial implementation of the heterogeneously catalyzed CO hydrogenation to higher alcohols is highly desired, but deeper insights into the reaction mechanisms and active sites are still needed. This review summarizes the established and well-investigated cobalt-based catalysts and the mechanisms resulting in oxygenate formation. Recently, a cobalt-based system derived from Mn-Co-based Prussian blue analogs by pyrolysis has shown great potential for higher-alcohol synthesis. In addition to the heterogeneously catalyzed reaction pathways involved in Fischer-Tropsch synthesis and methanol synthesis, the homogeneously catalyzed reaction pathways like reductive olefin hydroformylation and reductive primary alcohol carbonylation were found to play a key role.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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