Octa­kis(di­butyl­ammonium) deca­molybdate(VI)

IUCrData Pub Date : 2024-05-01 DOI:10.1107/S2414314624004632
Papa Aly Gueye , Lamine Yaffa , Dame Seye , Daouda Ndoye , Bocar Traoré , Mamadou Sidibé , Cheikh Abdoul Khadir Diop , Sergiu Shova , M. Weil (Editor)
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引用次数: 0

Abstract

(C8H20N)8[Mo10O34] comprises a centrosymmetric deca­molybdate polyanion linked through N—H⋯O hydrogen bonds to di­butyl­ammonium counter-cations.

In the title salt, (C8H20N)8[Mo10O34], the [Mo10O34]8− polyanion is located about an inversion centre and can be considered as a β-type octa­molybdate anion to which two additional MoO4 tetra­hedra are linked via common corners. The [Mo10O34]8− polyanions are packed in rows extending parallel to [001] and are connected to the di­butyl­ammonium counter-cations through N—H⋯O hydrogen-bonding inter­actions.

  1. Download : Download high-res image (333KB)
  2. Download : Download full-size image

十钼酸八(二丁基铵)(VI)。
在标题盐 (C8H20N)8[Mo10O34]中,[Mo10O34]8- 聚阴离子位于一个反转中心附近,可视为一个 β 型八钼酸盐阴离子,另外两个 MoO4 四面体通过共角与之相连。Mo10O34]8- 聚阴离子成行排列,平行于 [001] 延伸,并通过 N-H⋯O 氢键相互作用与二丁基铵反阳离子相连。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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CiteScore
0.30
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