Octakis(dibutylammonium) decamolybdate(VI)

IUCrData Pub Date : 2024-05-01 DOI:10.1107/S2414314624004632

Papa Aly Gueye , Lamine Yaffa , Dame Seye , Daouda Ndoye , Bocar Traoré , Mamadou Sidibé , Cheikh Abdoul Khadir Diop , Sergiu Shova , M. Weil (Editor)

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Abstract

(C₈H₂₀N)₈[Mo₁₀O₃₄] comprises a centrosymmetric decamolybdate polyanion linked through N—H⋯O hydrogen bonds to dibutylammonium counter-cations.

In the title salt, (C₈H₂₀N)₈[Mo₁₀O₃₄], the [Mo₁₀O₃₄]⁸⁻ polyanion is located about an inversion centre and can be considered as a β-type octamolybdate anion to which two additional MoO₄ tetrahedra are linked via common corners. The [Mo₁₀O₃₄]⁸⁻ polyanions are packed in rows extending parallel to [001] and are connected to the dibutylammonium counter-cations through N—H⋯O hydrogen-bonding interactions.

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十钼酸八(二丁基铵)(VI)。

在标题盐 (C8H20N)8[Mo10O34]中，[Mo10O34]8- 聚阴离子位于一个反转中心附近，可视为一个 β 型八钼酸盐阴离子，另外两个 MoO4 四面体通过共角与之相连。Mo10O34]8- 聚阴离子成行排列，平行于 [001] 延伸，并通过 N-H⋯O 氢键相互作用与二丁基铵反阳离子相连。

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