Tris[(pyridin-4-yl)methyl]phosphine, its P-oxide and CuI-based 1D polymer thereof

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-05-01 DOI:10.1016/j.mencom.2024.04.011

Maria P. Davydova, Taisiya S. Sukhikh, Alexander V. Artem’ev

引用次数: 0

Abstract

Tris[(pyridin-4-yl)methyl]phosphine and its P-oxide, new promising ligands, were obtained based on the reaction between 4-[(trimethylsilyl)methyl]pyridine and PCl₃. The coordination properties of tris[(pyridin-4-yl)methyl]phosphine oxide (L) were exemplified by the synthesis of a braided-shaped chain polymer [Cu₄I₄L₂] showing green luminescence at ambient temperature.

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三[(吡啶-4-基)甲基]膦、其 P-氧化物及其基于 CuI 的一维聚合物

根据 4-[(三甲基硅烷基)甲基]吡啶和 PCl3 的反应，获得了三[(吡啶-4-基)甲基]膦及其 P-氧化物，它们是新的有前途的配体。三[(吡啶-4-基)甲基]氧化膦（L）的配位特性体现在合成了一种编织链聚合物[Cu4I4L2]，该聚合物在常温下可发出绿色荧光。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.