Photochemical Vs Thermal Acid Catalysed Cyclization of Cannabigerol (CBG): An Unexpected Selectivity

IF 3 4区化学 Q3 CHEMISTRY, PHYSICAL

ChemPhotoChem Pub Date : 2024-05-31 DOI:10.1002/cptc.202400157

Arianna Bini, Prof. Mariella Mella, Prof. Daniele Merli, Prof. Stefano Protti

引用次数: 0

Abstract

The reactivity of Cannabigerol (CBG, 1) in organic solvents under photochemical and acid catalyzed conditions has been investigated in detail. The obtained results pointed out the presence of different reaction paths in the photochemical and the acid-catalyzed conditions, with a remarkable selectivity toward the formation of a 2,2-disubstituted-chromane derivative in the first case.

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光化学与热酸催化的大麻萜醇（CBG）环化：意想不到的选择性

我们详细研究了光化学和酸催化条件下大麻萜醇（CBG，1）在有机溶剂中的反应性。研究结果表明，在光化学和酸催化条件下存在不同的反应路径，在第一种情况下，生成 2,2-二取代-铬烷衍生物具有显著的选择性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ChemPhotoChem Chemistry-Physical and Theoretical Chemistry

CiteScore

5.80

自引率

5.40%

发文量

165

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