Subcritical water conversion of biomass to biofuels, chemicals and materials: a review

IF 15 2区 环境科学与生态学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Kapil Khandelwal, Somaye Seraj, Sonil Nanda, Ramin Azargohar, Ajay K. Dalai
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引用次数: 0

Abstract

The use of fossil fuels has been essential to the development of society, but has also contributed partly to global warming. For example, carbon dioxide emissions from fossil fuels and industries have increased by 60% since 1990, calling for the recycling of modern biomass in the context of a carbon neutral economy. Here we review the hydrothermal conversion of biomass into biofuels, chemicals and biomaterials with emphasis on subcritical water properties, hydrolysis of biomass, steam explosion, fractionation, carbonization, liquefaction, gasification, and fractionation of bio-oil. We observe that hydrothermal conversion of biomass in the presence of water at subcritical conditions produces value-added compounds with high process efficiency. Subcritical water allows rapid reaction rates, low mass transfer resistance, and gas-like diffusivity.

Abstract Image

亚临界水将生物质转化为生物燃料、化学品和材料:综述
化石燃料的使用对社会发展至关重要,但也在一定程度上导致了全球变暖。例如,自 1990 年以来,化石燃料和工业的二氧化碳排放量增加了 60%,这就要求在碳中和经济的背景下对现代生物质进行回收利用。在此,我们回顾了将生物质水热转化为生物燃料、化学品和生物材料的过程,重点介绍了亚临界水特性、生物质水解、汽爆、分馏、碳化、液化、气化和生物油分馏。我们观察到,在亚临界状态下,生物质在有水存在的情况下进行水热转化,可以生产出具有高工艺效率的增值化合物。亚临界水允许快速的反应速率、较低的传质阻力和类似气体的扩散性。
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来源期刊
Environmental Chemistry Letters
Environmental Chemistry Letters 环境科学-工程:环境
CiteScore
32.00
自引率
7.00%
发文量
175
审稿时长
2 months
期刊介绍: Environmental Chemistry Letters explores the intersections of geology, chemistry, physics, and biology. Published articles are of paramount importance to the examination of both natural and engineered environments. The journal features original and review articles of exceptional significance, encompassing topics such as the characterization of natural and impacted environments, the behavior, prevention, treatment, and control of mineral, organic, and radioactive pollutants. It also delves into interfacial studies involving diverse media like soil, sediment, water, air, organisms, and food. Additionally, the journal covers green chemistry, environmentally friendly synthetic pathways, alternative fuels, ecotoxicology, risk assessment, environmental processes and modeling, environmental technologies, remediation and control, and environmental analytical chemistry using biomolecular tools and tracers.
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