Dead Lithium in Lithium Metal Batteries: Formation, Characterization and Strategies

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yongming Jiang, Fangmin Ye
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引用次数: 0

Abstract

Lithium (Li) metal anode (LMA) replacing graphite anode for developing Li metal batteries (LMB) with the higher energy density has attracted much attention. However, LMA faces many issues, e. g., Li dendrites, dead Li and the side reactions, which causes the safety hazards and low coulomb efficiency (CE) of battery, therefore, LMB still cannot replace the current Li ion battery for practical use. Among those issues, dead Li is one of the decisive factors affecting the CE of LMB. To better understand dead Li, we summarize the recent work about the generation of dead Li, its impact on batteries performance, and the strategies to reuse and eliminate dead Li. Finally, the prospect of the future LMA and resultant LMB is also put forward.

Abstract Image

金属锂电池中的死锂:锂金属电池中的死锂:形成、特性和策略。
锂(Li)金属阳极(LMA)取代石墨阳极以开发能量密度更高的锂金属电池(LMB)已引起广泛关注。然而,LMA 面临着许多问题,例如锂枝晶、死锂和副反应,这些问题会造成电池的安全隐患和低库仑效率(CE),因此 LMB 仍无法取代目前的锂离子电池投入实际使用。在这些问题中,死锂是影响锂电池CE的决定性因素之一。为了更好地理解死锂,我们总结了近期有关死锂的产生、死锂对电池性能的影响以及再利用和消除死锂的策略等方面的工作。最后,我们还对未来的 LMA 和由此产生的 LMB 进行了展望。
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来源期刊
Chemistry - A European Journal
Chemistry - A European Journal 化学-化学综合
CiteScore
7.90
自引率
4.70%
发文量
1808
审稿时长
1.8 months
期刊介绍: Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields. Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world. All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times. The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems. Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.
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