Palladium-Iron Bimetallic-Catalyzed Cross-Coupling Reaction of Alcohols and Nitroarenes Using a Hydrogen-Transfer Redox System

IF 1.4 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Letters Pub Date : 2024-05-17 DOI:10.1093/chemle/upae094

Rikiya Horikawa, Shoma Ishii, Urara Shinozaki, Reika Midorikawa, Takamichi Mori, Masanari Kimura

引用次数: 0

Abstract

A Pd/Fe bimetallic catalyst in the presence of the Xantphos ligand promoted the cross-coupling reaction of alcohols and nitroarenes via a hydrogen-transfer redox system. The consecutive formation of aldimines from benzyl alcohols and nitroarenes proceeded in three steps in a single manipulation: oxidation of alcohols, reduction of nitroarenes, and dehydrative condensation of aldehydes and aminoarenes.

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利用氢转移氧化还原体系进行钯铁双金属催化的醇和硝基烯烃交叉偶联反应

存在 Xantphos 配体的钯/铁双金属催化剂通过氢转移氧化还原系统促进了醇和硝基烯烃的交叉偶联反应。苄醇和硝基烯烃在一次操作中通过三个步骤连续生成醛亚胺：醇的氧化、硝基烯烃的还原以及醛和氨基烯烃的脱水缩合。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemistry Letters 化学-化学综合

CiteScore

3.00

自引率

6.20%

发文量

260

审稿时长

1.2 months

期刊介绍： Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry