Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure

IF 1.1 3区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR
I. V. Skabitskii, S. S. Shapovalov
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引用次数: 0

Abstract

The reaction of TpReOCl(StBu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(µ-StBu)]2(µ-S2) (I). Complex I can also be synthesized by the reaction of TpReO(StBu)2 with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]2(µ-S2)(µ-S) (II) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex I with dichloromethane containing the molecules with different conformations of the Re2S2 fragment (Ia and Ib) and complex II are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for Ia, Ib, and II, respectively).

Abstract Image

Abstract Image

具有二硫桥配体的三(吡唑基)硼酸铼(V)硫酸盐配合物:合成与结构
摘要TpReOCl(StBu)(Tp = 三(吡唑基)硼酸阴离子)与二硫化钠在二甲氧基乙烷中反应生成了新的双核铼络合物 [TpReO(µ-StBu)]2(µ-S2)(I)。络合物 I 还可以通过 TpReO(StBu)2 与溴化锰(II)悬浮液在甲苯中的反应合成,同时对其中一个配体进行脱烷基化,形成另一个含有桥接硫化物和二硫化物配体的新络合物 [TpReO]2(µ-S2)(µ-S)(II)。通过 X 射线衍射 (XRD)(CIF 文件ССDC 编号 2262677、2262678 和 2267423,分别代表 Ia、Ib 和 II)研究了络合物 I 与二氯甲烷的两种结晶溶液的结构,其中络合物 I 含有不同构象的 Re2S2 片段分子(Ia 和 Ib),络合物 II 含有不同构象的 Re2S2 片段分子(Ia 和 Ib)。
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来源期刊
Russian Journal of Coordination Chemistry
Russian Journal of Coordination Chemistry 化学-无机化学与核化学
CiteScore
2.40
自引率
15.80%
发文量
85
审稿时长
7.2 months
期刊介绍: Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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