Effect of B2O3 on Optical Properties of Dy3+ Ion-Doped Zinc–Aluminum–Sodium–Phosphate Glasses

IF 0.8 4区 化学 Q4 SPECTROSCOPY
K. Brahmachary, G. Giribabu, Rajesh Dagupati, M. Dhamodhara Naidu
{"title":"Effect of B2O3 on Optical Properties of Dy3+ Ion-Doped Zinc–Aluminum–Sodium–Phosphate Glasses","authors":"K. Brahmachary,&nbsp;G. Giribabu,&nbsp;Rajesh Dagupati,&nbsp;M. Dhamodhara Naidu","doi":"10.1007/s10812-024-01731-x","DOIUrl":null,"url":null,"abstract":"<p>Different concentrations of B<sub>2</sub>O<sub>3</sub> in zinc–aluminum–sodium–phosphate (ZANP) glasses were synthesized by the conventional melt-quenching method and analyzed using X-ray diffraction (XRD), optical absorption, excitation, visible luminescence, decay lifetime, and chromaticity methods. The amorphous nature of the glasses was confirmed by the absence of sharp diffraction peaks in the XRD profile. In the visible emission spectra blue, yellow, and red bands were observed and the intensity of the yellow band was superior. Furthermore, the samples show a luminescence quenching beyond 20 mol.% of B<sub>2</sub>O<sub>3</sub> concentration. The decay lifetime of <sup>4</sup>F<sub>9/2</sub> of Dy<sup>3+</sup> ions was found to be maximal in ZANP Dy0.5:20B<sub>2</sub>O<sub>3</sub> glass.</p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-024-01731-x","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
引用次数: 0

Abstract

Different concentrations of B2O3 in zinc–aluminum–sodium–phosphate (ZANP) glasses were synthesized by the conventional melt-quenching method and analyzed using X-ray diffraction (XRD), optical absorption, excitation, visible luminescence, decay lifetime, and chromaticity methods. The amorphous nature of the glasses was confirmed by the absence of sharp diffraction peaks in the XRD profile. In the visible emission spectra blue, yellow, and red bands were observed and the intensity of the yellow band was superior. Furthermore, the samples show a luminescence quenching beyond 20 mol.% of B2O3 concentration. The decay lifetime of 4F9/2 of Dy3+ ions was found to be maximal in ZANP Dy0.5:20B2O3 glass.

B2O3 对掺杂 Dy3+ 离子的锌铝磷酸钠玻璃光学特性的影响
采用传统的熔淬法合成了不同浓度的磷酸锌铝钠(ZANP)玻璃中的 B2O3,并使用 X 射线衍射(XRD)、光吸收、激发、可见光发光、衰减寿命和色度方法对其进行了分析。X 射线衍射曲线中没有尖锐的衍射峰,这证实了玻璃的无定形性质。在可见光发射光谱中观察到蓝色、黄色和红色条带,其中黄色条带的强度更高。此外,当 B2O3 浓度超过 20 摩尔/% 时,样品会出现发光淬灭现象。在 ZANP Dy0.5:20B2O3 玻璃中,Dy3+ 离子 4F9/2 的衰变寿命达到最大。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信