Discussion on the studies of position-specific carbon isotopes of propane by Li et al. (2018), Zhang et al. (2022) and Shuai et al. (2023)

IF 2.6 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Juske Horita
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引用次数: 0

Abstract

In a series of recent publications in Organic Geochemistry and elsewhere, investigators from State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry and their collaborators have reported position-specific δ13C of propane obtained from natural reservoirs and pyrolysis experiments. Based solely on the very negative ΔC-T values (δ13Ccenter – δ13Cterminal), ranging from −7 to −10 ‰, they advocated for abiogenic origins of the propanes from sedimentary settings (shale and coal deposits). However, they never demonstrated accuracy of the data and it is likely that correct ΔC-T values for these propanes are close to zero ‰. Therefore, their discussion and interpretation in terms of geochemical processes, including a putative abiogenic origin, are not substantiated.

关于李等人(2018)、张等人(2022)和帅等人(2023)对丙烷位置特异性碳同位素研究的讨论
有机地球化学国家重点实验室、广州地球化学研究所的研究人员及其合作者最近在《有机地球化学》等刊物上发表了一系列文章,报告了从天然储层和热解实验中获得的丙烷的特定位置δ13C。他们仅根据非常负的 ΔC-T 值(δ13C 中心-δ13C 末端)(范围在 -7 至 -10 ‰ 之间),就认为丙烷来自沉积环境(页岩和煤沉积)。然而,他们从未证明数据的准确性,而且这些丙烷的正确 ΔC-T 值很可能接近零‰。因此,他们在地球化学过程方面的讨论和解释,包括假定的非生物起源,都没有得到证实。
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来源期刊
Organic Geochemistry
Organic Geochemistry 地学-地球化学与地球物理
CiteScore
5.50
自引率
6.70%
发文量
100
审稿时长
61 days
期刊介绍: Organic Geochemistry serves as the only dedicated medium for the publication of peer-reviewed research on all phases of geochemistry in which organic compounds play a major role. The Editors welcome contributions covering a wide spectrum of subjects in the geosciences broadly based on organic chemistry (including molecular and isotopic geochemistry), and involving geology, biogeochemistry, environmental geochemistry, chemical oceanography and hydrology. The scope of the journal includes research involving petroleum (including natural gas), coal, organic matter in the aqueous environment and recent sediments, organic-rich rocks and soils and the role of organics in the geochemical cycling of the elements. Sedimentological, paleontological and organic petrographic studies will also be considered for publication, provided that they are geochemically oriented. Papers cover the full range of research activities in organic geochemistry, and include comprehensive review articles, technical communications, discussion/reply correspondence and short technical notes. Peer-reviews organised through three Chief Editors and a staff of Associate Editors, are conducted by well known, respected scientists from academia, government and industry. The journal also publishes reviews of books, announcements of important conferences and meetings and other matters of direct interest to the organic geochemical community.
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