Magneto-Optics of Dy3+ Ion in Low-Symmetric Orthoaluminate Structure

IF 0.6 4区 材料科学 Q4 CRYSTALLOGRAPHY
U. V. Valiev, M. E. Malysheva, V. O. Pelenovich, A. X. Ramazanov, F. K. Turotov, D. N. Karimov
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Abstract

Magnetic susceptibility and the Faraday effect in orthorhombic DyAlO3 single crystals were studied along the crystallographic b-axis, the axis of easy magnetization, in a temperature range 78–300 K. The Faraday rotation was measured on the basis of the temperature and spectral dependencies of the rotation angles θ of the major axis of the ellipse of light radiation polarization in a wavelength range 440–750 nm. At a wavelength of 506 nm, the dependence of the Verdet constant V on the magnetic susceptibility χM was observed to be linear in a temperature range 85–300 K, and the paramagnetic Verdet constant Cp was calculated. A comparative analysis of the constants Cp and the effective frequencies ω0 of allowed transitions in cubic R3Al5O12 garnets and RAlO3 (R = Tb3+, Dy3+) orthoaluminate crystals was carried out in terms of the local site symmetry for rare-earth ions. The possibility of practical magneto-optical applications of the DyAlO3 crystals is briefly discussed.

Abstract Image

低对称正铝酸盐结构中 Dy3+ 离子的磁光学特性
摘要 研究了正交菱形 DyAlO3 单晶在 78-300 K 温度范围内沿晶体学 b 轴(即易磁化轴)的磁感应强度和法拉第效应,并根据波长范围为 440-750 nm 的光辐射偏振椭圆主轴旋转角 θ 的温度和光谱依赖性测量了法拉第旋转。在波长为 506 nm 时,观察到 Verdet 常数 V 与磁感应强度 χM 在 85-300 K 温度范围内呈线性关系,并计算出顺磁性 Verdet 常数 Cp。根据稀土离子的局部位点对称性,对立方 R3Al5O12 石榴石和 RAlO3(R = Tb3+、Dy3+)正铝酸盐晶体中允许转变的常数 Cp 和有效频率 ω0 进行了比较分析。简要讨论了 DyAlO3 晶体实际磁光应用的可能性。
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来源期刊
Crystallography Reports
Crystallography Reports 化学-晶体学
CiteScore
1.10
自引率
28.60%
发文量
96
审稿时长
4-8 weeks
期刊介绍: Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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