M. Ya. Goikhman, I. V. Podeshvo, N. L. Loretsyan, I. V. Gofman, V. D. Krasikov, I. I. Malakhova, L. S. Litvinova, E. N. Bykova, I. A. Nasirova, A. V. Yakimansky
{"title":"Polymers with [2,2′-Biquinoline]-diyldimethanamine Units in the Main Chain and Their Metal–Polymer Complexes with Copper(I)","authors":"M. Ya. Goikhman, I. V. Podeshvo, N. L. Loretsyan, I. V. Gofman, V. D. Krasikov, I. I. Malakhova, L. S. Litvinova, E. N. Bykova, I. A. Nasirova, A. V. Yakimansky","doi":"10.1134/S0965545X24600121","DOIUrl":null,"url":null,"abstract":"<p>New monomers of the biquinoline series—diyldimethanamines—have been synthesized, and polymers having biquinoline units in the main chain and their metal–polymer complexes with cuprous chloride have been obtained using these monomers. The resulting starting compounds and polymers have been studied using NMR spectroscopy, HPLC, and simultaneous thermal (thermogravimetric and differential thermal) analysis, and the mechanical characteristics of the polymers and metal–polymer complexes have been examined. It has been shown that the structure and physicochemical properties of the polymers based on synthesized diyldimethanediamines largely depend on the position of groups in the biquinoline moiety and the presence of interchain coordination bonds in the polymer.</p>","PeriodicalId":738,"journal":{"name":"Polymer Science, Series A","volume":"65 6","pages":"645 - 654"},"PeriodicalIF":1.0000,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series A","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S0965545X24600121","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
New monomers of the biquinoline series—diyldimethanamines—have been synthesized, and polymers having biquinoline units in the main chain and their metal–polymer complexes with cuprous chloride have been obtained using these monomers. The resulting starting compounds and polymers have been studied using NMR spectroscopy, HPLC, and simultaneous thermal (thermogravimetric and differential thermal) analysis, and the mechanical characteristics of the polymers and metal–polymer complexes have been examined. It has been shown that the structure and physicochemical properties of the polymers based on synthesized diyldimethanediamines largely depend on the position of groups in the biquinoline moiety and the presence of interchain coordination bonds in the polymer.
期刊介绍：
Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
