{"title":"Hydrindacene‐Based Zinc Aryl Thiolate and Aryl Selenolate Zn(EMSFluind)2 (E = S, Se)","authors":"Jens Beckmann, Pascal Komorr, Pim Puylaert","doi":"10.1002/zaac.202400052","DOIUrl":null,"url":null,"abstract":"The bulky aryl thiol, MSFluindSH (1S), and aryl selenol, MSFluindSeH (1Se), possessing a tetramethyl‐s‐hydrindacen‐4’‐yl‐(Rind)‐based substituent containing two fluorenyl groups in 9 and 9’‐positions, were prepared (MSFluind = dispiro[fluorene‐9,3’‐(1’,1’,7’,7’‐tetramethyl‐s‐hydrindacene‐4’‐yl)‐5’,9’’‐fluorene]). The reaction of 1S and 1Se with Et2Zn provided a monomeric zinc aryl thiolate, Zn(SMSFluind)2 (2S), and zinc aryl selenolate, Zn(SeMSFluind)2 (2Se), with essentially two‐coordinate zinc atoms.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"2012 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400052","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The bulky aryl thiol, MSFluindSH (1S), and aryl selenol, MSFluindSeH (1Se), possessing a tetramethyl‐s‐hydrindacen‐4’‐yl‐(Rind)‐based substituent containing two fluorenyl groups in 9 and 9’‐positions, were prepared (MSFluind = dispiro[fluorene‐9,3’‐(1’,1’,7’,7’‐tetramethyl‐s‐hydrindacene‐4’‐yl)‐5’,9’’‐fluorene]). The reaction of 1S and 1Se with Et2Zn provided a monomeric zinc aryl thiolate, Zn(SMSFluind)2 (2S), and zinc aryl selenolate, Zn(SeMSFluind)2 (2Se), with essentially two‐coordinate zinc atoms.
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