Highly site-selective C(sp3)–H bond functionalization enabled by framework confinements

IF 11.5 Q1 CHEMISTRY, PHYSICAL

Chem Catalysis Pub Date : 2024-04-18 DOI:10.1016/j.checat.2024.100961

Yuping Wang, Feihe Huang

引用次数: 0

Abstract

Mimicking enzymes’ ability to orient substrates through nanoconfinement holds significant promise for the development of artificial catalysts with enhanced performance. Recently in Chem, a cyclodextrin-based metal-organic framework has been shown to undergo selective C–H bond activation in the presence of guest molecules upon photoirradiation, illustrating a crucial advance in replicating biological catalysis within artificial matrices.

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利用框架限制实现高位点选择性 C（sp3）-H 键官能化

通过纳米纤化模仿酶定向底物的能力为开发性能更强的人工催化剂带来了巨大希望。最近在《化学》杂志上，一种基于环糊精的金属有机框架在客体分子存在的情况下，经光照射后可选择性地激活 C-H 键，这表明在人工基质中复制生物催化作用取得了重要进展。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chem Catalysis

CiteScore

10.50

自引率

6.40%

发文量

期刊介绍： Chem Catalysis is a monthly journal that publishes innovative research on fundamental and applied catalysis, providing a platform for researchers across chemistry, chemical engineering, and related fields. It serves as a premier resource for scientists and engineers in academia and industry, covering heterogeneous, homogeneous, and biocatalysis. Emphasizing transformative methods and technologies, the journal aims to advance understanding, introduce novel catalysts, and connect fundamental insights to real-world applications for societal benefit.

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