Thiol-Ene Photo Crosslinked PUA-PUMA-Based Flexible Gel Polymer Electrolyte for Lithium-Ion Batteries

IF 4.2 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Macromolecular Materials and Engineering Pub Date : 2024-04-13 DOI:10.1002/mame.202400051

Fatmanur Uyumaz, Elmira Nurgaziyeva, Sandugash Kalybekkyzy, Memet Vezir Kahraman

引用次数: 0

Abstract

Crosslinked polymer films, formed via sol–gel and UV photocrosslinking, serve as gel polymer electrolytes (GPEs) in lithium-ion batteries. Combining polyurethane acrylate (PUA), polyurethane methacrylate (PUMA), pentaerythritol tetrakis (3-mercaptopropionate) (PETMP), and 3-mercaptopropyl trimetoxysilane (MPTMS) yields flexible membranes, enhancing stability and liquid electrolyte compatibility. The resulting GPE displays higher ionic conductivity (1.46 × 10⁻³ S cm⁻¹) than Celgrad2500, with PUA-PUMA's hydrophilicity and PETMP's SH groups preventing leakage. GPPF1, the developed GPE, offers improved ionic conductivity, a stable electrochemical window up to 3.8 V, and heightened safety for versatile energy storage systems.

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用于锂离子电池的硫醇-烯光交联 PUA-PUMA 基柔性凝胶聚合物电解质

通过溶胶-凝胶和紫外光交联形成的交联聚合物薄膜可用作锂离子电池中的凝胶聚合物电解质（GPE）。将聚氨酯丙烯酸酯 (PUA)、聚氨酯甲基丙烯酸酯 (PUMA)、季戊四醇四（3-巯基丙酸）酯 (PETMP) 和 3-巯基丙基三甲氧基硅烷 (MPTMS) 结合在一起可产生柔性膜，提高稳定性和液态电解质兼容性。由于 PUA-PUMA 的亲水性和 PETMP 的 SH 基团可防止泄漏，因此生成的 GPE 比 Celgrad2500 显示出更高的离子电导率（1.46 × 10-3 S cm-1）。所开发的 GPE GPPF1 具有更高的离子电导率、高达 3.8 V 的稳定电化学窗口和更高的安全性，可用于多功能储能系统。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Macromolecular Materials and Engineering 工程技术-材料科学：综合

CiteScore

7.30

自引率

5.10%

发文量

328

审稿时长

1.6 months

期刊介绍： Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)