NHC-Catalyzed Enantioselective Transformations Involving α-Bromoenals

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical record Pub Date : 2024-04-08 DOI:10.1002/tcr.202400005

Fatemeh Doraghi, Mahmoud Ameli, Shirin Ansariashlaghi, Bagher Larijani, Mohammad Mahdavi

引用次数: 0

Abstract

α-Haloenals, especially, α-bromoenals considered as one of the important building blocks in organic synthesis. They can participate in various (3+2)-, (3+3)-, (3+4)-, and (2+4)-annulation reactions with other organic molecules in the presence of an NHC catalyst to produce enantioenriched carbo-, and heterocyclic compounds. Herein, we have described NHC-catalyzed enantioselective transformations of α-bromoenals in the synthesis of various heterocycles, and carbocycles, as well as acyclic organic compounds.

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NHC 催化的涉及 α-溴烯醛的对映选择性转化

α-烯醛，尤其是 α-溴烯醛，被认为是有机合成中的重要构件之一。在 NHC 催化剂的作用下，它们可以与其他有机分子发生各种 (3+2)-、(3+3)-、(3+4)- 和 (2+4)-annulation 反应，生成对映体丰富的碳水化合物和杂环化合物。在此，我们介绍了在 NHC 催化下，α-溴烯醛在合成各种杂环和碳环以及无环有机化合物过程中的对映选择性转化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical record 化学-化学综合

CiteScore

11.00

自引率

3.00%

发文量

188

审稿时长

>12 weeks

期刊介绍： The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.