Research Progress in Structure Synthesis, Properties, and Applications of Small-Molecule Silicone Surfactants

IF 8.6 2区化学 Q1 Chemistry

Topics in Current Chemistry Pub Date : 2024-04-08 DOI:10.1007/s41061-024-00457-w

Wenhui Zhao, Yuqiao Cheng, Jiaqi Pu, Leigang Su, Nan Wang, Yinhao Cao, Lijun Liu

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Abstract

Silicone surfactants have garnered significant research attention owing to their superior properties, such as wettability, ductility, and permeability. Small-molecular silicone surfactants with simple molecular structures outperform polymeric silicone surfactants in terms of surface activity, emulsification, wetting, foaming, and other areas. Moreover, silicone surfactants with small molecules exhibit a diverse and rich molecular structure. This review discusses various synthetic routes for the synthesis of different classes of surfactants, including single-chain, “umbrella” structure, double chain, bolaform, Gemini, and stimulus-responsive surfactants. The fundamental surface/interface properties of the synthesized surfactants are also highlighted. Additionally, these surfactants have demonstrated enormous potential in agricultural synergism, drug delivery, mineral flotation, enhanced oil recovery, separation, and extraction, and foam fire-fighting.

Graphical Abstract

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小分子有机硅表面活性剂的结构合成、性能和应用研究进展

有机硅表面活性剂因其润湿性、延展性和渗透性等优越性能而备受研究关注。分子结构简单的小分子有机硅表面活性剂在表面活性、乳化、润湿、发泡等方面均优于聚合物有机硅表面活性剂。此外，小分子有机硅表面活性剂的分子结构多样而丰富。本综述讨论了合成不同类别表面活性剂的各种合成路线，包括单链、"伞状 "结构、双链、波拉莫夫型、双子型和刺激响应型表面活性剂。此外，还重点介绍了合成表面活性剂的基本表面/界面特性。此外，这些表面活性剂在农业增效、药物输送、矿物浮选、提高石油采收率、分离和萃取以及泡沫灭火等方面都显示出巨大的潜力。

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来源期刊

Topics in Current Chemistry 化学-化学综合

CiteScore

11.70

自引率

1.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science. Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community. In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.