The Difunctionalization of Alkenes Completed by DMTSM and CF3SO2Na without Metal Catalysts

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC

Synlett Pub Date : 2024-03-22 DOI:10.1055/a-2283-5928

Siwei Shen, Jinzhao Gao, Xiaofeng Luo, Tianqiang Wang, Peihua Liu, Rulong Yan

引用次数: 0

Abstract

The electrophilic thiolation of alkenes initiated by DMTSM and the addition of CF₃SO₂Na in one pot has been developed. This reaction also can be extended to ArSO₂Na. This protocol features a good substrate scope, simple procedures, and mild reaction conditions and affords the desired products in moderate yields without metal catalysts.

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DMTSM 和 CF3SO2Na 在不使用金属催化剂的情况下完成的烯烃双官能化反应

通过 DMTSM 和 CF3SO2Na 的一锅加成，开发出了烯烃的亲电硫代反应。该反应还可扩展至 ArSO2Na。该方案具有底物范围广、操作简单、反应条件温和等特点，无需金属催化剂就能以中等产率得到所需的产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Synlett 化学-有机化学

CiteScore

3.40

自引率

5.00%

发文量

369

审稿时长

1 months

期刊介绍： SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.