Micro to macro investigation of clays advising their constitutive modelling - part I

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Federica Cotecchia, S. Guglielmi, F. Cafaro, Antonio Gens
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引用次数: 0

Abstract

This keynote lecture discusses the results of a long lasting experimental research, devoted to the investigation of clay microstructure and its evolution upon loading. Micro-scale analyses, involving scanning electron microscopy, image processing, mercury intrusion porosimetry and swelling paths to test the clay bonding, are presented on clays subjected to different loading paths, with the purpose of providing experimental evidence of the processes at the micro-scale which underlie the clay response at the macro-scale. Data from the literature on clays of different classes, either soft or stiff, are compared to original results on two stiff clays, Pappadai and Lucera clay, both in their natural state and after reconstitution in the laboratory. The results presented herein allow building a conceptual model of the evolution of clay microstructure upon different loading paths, providing microstructural insights into the macro-behaviour described by constitutive laws and advising their mathematical formalization in the framework of either continuum mechanics or micro-mechanics. For editorial purposes, the research results are presented in two parts. The first part, presented in this paper, concerns the results for reconstituted clays, whereas a second part, concerning the corresponding natural clays, is discussed in a second companion paper.
粘土从微观到宏观的研究,为其构造建模提供建议--第一部分
本主题演讲讨论了一项长期实验研究的成果,该研究致力于调查粘土的微观结构及其在加载时的演变。微观尺度分析包括扫描电子显微镜、图像处理、汞侵入孔隙模拟法和膨胀路径测试粘土粘结力,这些分析是针对不同加载路径下的粘土进行的,目的是为微观尺度上的过程提供实验证据,而微观尺度上的过程是粘土宏观尺度反应的基础。文献中关于不同类别粘土(软粘土或硬粘土)的数据与 Pappadai 和 Lucera 两种硬粘土在自然状态和实验室重组后的原始结果进行了比较。本文介绍的结果有助于建立粘土微观结构在不同加载路径下演变的概念模型,从微观结构上深入了解构成定律所描述的宏观行为,并建议在连续介质力学或微观力学框架内对其进行数学形式化。为便于编辑,研究成果分为两部分。本文介绍的第一部分涉及重组粘土的结果,而第二部分涉及相应的天然粘土,将在第二篇配套论文中讨论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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