Prebiotic Astrochemistry from Astronomical Observations and Laboratory Spectroscopy.

IF 11.7 1区 化学 Q1 CHEMISTRY, PHYSICAL
Lucy M Ziurys
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Abstract

The discovery of more than 200 gas-phase chemical compounds in interstellar space has led to the speculation that this nonterrestrial synthesis may play a role in the origin of life. These identifications were possible because of laboratory spectroscopy, which provides the molecular fingerprints for astronomical observations. Interstellar chemistry produces a wide range of small, organic molecules in dense clouds, such as NH2COCH3, CH3OCH3, CH3COOCH3, and CH2(OH)CHO. Carbon (C) is also carried in the fullerenes C60 and C70, which can preserve C-C bonds from circumstellar environments for future synthesis. Elusive phosphorus has now been found in molecular clouds, the sites of star formation, in the molecules PO and PN. Such clouds can collapse into solar systems, although the chemical/physical processing of the emerging planetary disk is uncertain. The presence of molecule-rich interstellar starting material, as well as the link to planetary bodies such as meteorites and comets, suggests that astrochemical processes set a prebiotic foundation.

从天文观测和实验室光谱学看前生物天体化学。
星际空间中 200 多种气相化合物的发现,使人们猜测这种非地球合成物可能在生命起源中发挥作用。实验室光谱学为天文观测提供了分子指纹,因此这些鉴定成为可能。星际化学在稠密云层中产生了多种有机小分子,如 NH2COCH3、CH3OCH3、CH3COOCH3 和 CH2(OH)CHO。富勒烯 C60 和 C70 中也含有碳(C),它们可以保存周星体环境中的 C-C 键,用于未来的合成。在恒星形成的场所--分子云中,现在已经在 PO 和 PN 分子中发现了难以捉摸的磷。这种云可以坍缩成太阳系,尽管新出现的行星盘的化学/物理过程还不确定。富含分子的星际起始物质的存在,以及与陨石和彗星等行星体的联系,表明天体化学过程奠定了前生物的基础。物理化学年刊》第 75 卷的最终在线出版日期预计为 2024 年 4 月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
28.00
自引率
0.00%
发文量
21
期刊介绍: The Annual Review of Physical Chemistry has been published since 1950 and is a comprehensive resource for significant advancements in the field. It encompasses various sub-disciplines such as biophysical chemistry, chemical kinetics, colloids, electrochemistry, geochemistry and cosmochemistry, chemistry of the atmosphere and climate, laser chemistry and ultrafast processes, the liquid state, magnetic resonance, physical organic chemistry, polymers and macromolecules, and others.
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