DBU-catalyzed selective β-addition of α-fluoro nitroalkanes to allenoates

IF 1.7 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Fluorine Chemistry Pub Date : 2024-01-17 DOI:10.1016/j.jfluchem.2024.110255

Li-Wen Ning, Yi-Hu Jin, Ren-Jie Wang, Youcan Zhang, Ya Li

引用次数: 0

Abstract

An efficient DBU-catalyzed β-addition of α-fluoro nitroalkane compounds to allenoates has been developed. Both γ-substituted and -unsubstituted allenoates participated in the reaction, giving a series of the β-addition products bearing a stereogenic carbon-fluorine structural unit in very good yields. The practicability of the method was also demonstrated.

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DBU 催化的 α-氟硝基烷烃与异戊烯酸酯的选择性 β-加成反应

研究人员开发了一种高效的 DBU 催化 α-氟硝基烷烃化合物与烯酸盐的β-加成反应。γ-取代和-未取代的异烯酸酯都参与了反应，以非常好的收率得到了一系列带有立体碳-氟结构单元的 β-加成产物。该方法的实用性也得到了证明。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Fluorine Chemistry 化学-无机化学与核化学

CiteScore

3.80

自引率

10.50%

发文量

审稿时长

33 days

期刊介绍： The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature. For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.