{"title":"Study on Methane Displacement Law of Coal with Different Metamorphic Degrees by N2 Injection","authors":"C. Ding, Z. Li","doi":"10.3103/S0361521923070029","DOIUrl":null,"url":null,"abstract":"<p>To reveal the mechanism of gas displacement in coal seam by N<sub>2</sub>, the desorption behavior of CH<sub>4</sub> after N<sub>2</sub> injection was studied by using giant canonical ensemble Monte Carlo (GCMC) and molecular dynamics (MD) methods. Through the adsorption and replacement of CH<sub>4</sub> by N<sub>2</sub> on three kinds of coal samples, the influence of different metamorphic coals on the replacement of CH<sub>4</sub> by N<sub>2</sub> was analyzed from the replacement amount and injection ratio. The results show that the average relative concentration of CH<sub>4</sub> in vacuum layer increases after N<sub>2</sub> implantation. The more N<sub>2</sub> injection pressure, the more gas desorption. It can be seen from the two indexes of replacement amount and replacement ratio that CH<sub>4</sub> replacement amount is positively correlated with coal metamorphic degree, while N<sub>2</sub> injection ratio is negatively correlated with coal metamorphic degree. In the same coal, CH<sub>4</sub> replacement amount is positively correlated with pressure, while N<sub>2</sub> injection ratio is negatively correlated with pressure.</p>","PeriodicalId":779,"journal":{"name":"Solid Fuel Chemistry","volume":"57 1 supplement","pages":"S20 - S26"},"PeriodicalIF":0.8000,"publicationDate":"2024-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid Fuel Chemistry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.3103/S0361521923070029","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
To reveal the mechanism of gas displacement in coal seam by N2, the desorption behavior of CH4 after N2 injection was studied by using giant canonical ensemble Monte Carlo (GCMC) and molecular dynamics (MD) methods. Through the adsorption and replacement of CH4 by N2 on three kinds of coal samples, the influence of different metamorphic coals on the replacement of CH4 by N2 was analyzed from the replacement amount and injection ratio. The results show that the average relative concentration of CH4 in vacuum layer increases after N2 implantation. The more N2 injection pressure, the more gas desorption. It can be seen from the two indexes of replacement amount and replacement ratio that CH4 replacement amount is positively correlated with coal metamorphic degree, while N2 injection ratio is negatively correlated with coal metamorphic degree. In the same coal, CH4 replacement amount is positively correlated with pressure, while N2 injection ratio is negatively correlated with pressure.
期刊介绍:
The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.