Synthesis and single crystal X-ray studies of bis-(trimethylsilylmethyl) tellurium diiodide through an insertion route

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-01-09 DOI:10.3233/mgc-230101

Amit K. Tripathi, Priyanka Singh, Ray J. Butcher, J. Bera, Puspendra Singh

引用次数: 0

Abstract

The synthesis and single crystal X-ray studies of bis(trimethylsilylmethyl) telluriumdiiodide was studied through an insertion route with quantitative yield. This molecule was characterized with the help of 1H NMR, elemental analysis and single-crystal X-ray studies. The new crystalline molecule provides a supramolecular synthon in crystal lattices of tellurium(IV) diiodide showing 2d synthons associated with the help of C-H - - - I interactions.

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通过插入路线合成双-(三甲基硅甲基)二碘化碲并进行单晶 X 射线研究

通过插入路线研究了双(三甲基硅甲基)二碘化碲的合成和单晶 X 射线研究，并获得了定量收率。借助 1H NMR、元素分析和单晶 X 射线研究对该分子进行了表征。这种新的晶体分子在二碘化碲（IV）晶格中提供了一种超分子合成物，在 C-H - - I 相互作用的帮助下显示出 2d 合成物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.