{"title":"Modeling Silicon-Dominant Anodes: Parametrization, Discussion, and Validation of a Newman-Type Model","authors":"A. Durdel, S. Friedrich, Lukas Hüsken, A. Jossen","doi":"10.3390/batteries9110558","DOIUrl":null,"url":null,"abstract":"Silicon is a promising anode material and can already be found in commercially available lithium-ion cells. Reliable modeling and simulations of new active materials for lithium-ion batteries are becoming more and more important, especially regarding cost-efficient cell design. Because literature lacks an electrochemical model for silicon-dominant electrodes, this work aims to close the gap. To this end, a Newman p2D model for a lithium-ion cell with a silicon-dominant anode and a nickel-cobalt-aluminum-oxide cathode is parametrized. The micrometer silicon particles are partially lithiated to 1200mAh/gSi. The parametrization is based on values from the electrode manufacturing process, measured values using lab cells, and literature data. Charge and discharge tests at six different C-rates up to 2C serve as validation data, showing a root-mean-squared error of about 21mV and a deviation in discharge capacity of about 1.3 , both during a 1 C constant current discharge. Overall, a validated parametrization for a silicon-dominant anode is presented, which, to the best of our knowledge, is not yet available in literature. For future work, more in-depth studies should investigate the material parameters for silicon to expand the data available in the literature and facilitate further simulation work.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"1 1","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Batteries","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.3390/batteries9110558","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
Silicon is a promising anode material and can already be found in commercially available lithium-ion cells. Reliable modeling and simulations of new active materials for lithium-ion batteries are becoming more and more important, especially regarding cost-efficient cell design. Because literature lacks an electrochemical model for silicon-dominant electrodes, this work aims to close the gap. To this end, a Newman p2D model for a lithium-ion cell with a silicon-dominant anode and a nickel-cobalt-aluminum-oxide cathode is parametrized. The micrometer silicon particles are partially lithiated to 1200mAh/gSi. The parametrization is based on values from the electrode manufacturing process, measured values using lab cells, and literature data. Charge and discharge tests at six different C-rates up to 2C serve as validation data, showing a root-mean-squared error of about 21mV and a deviation in discharge capacity of about 1.3 , both during a 1 C constant current discharge. Overall, a validated parametrization for a silicon-dominant anode is presented, which, to the best of our knowledge, is not yet available in literature. For future work, more in-depth studies should investigate the material parameters for silicon to expand the data available in the literature and facilitate further simulation work.