Effect of the Surface modification of Cellulose nanofibers on the Mechanical Properties and Disintegrability of Specific PLA/Cellulose Composites

J. Wietecha, J. Kazimierczak, Agata Jeziorna
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Abstract

Abstract PLA/nanofibrillar cellulose (NFC) composite films were produced by solution casting. Before use, the cellulose fibers were modified with various types of surface active agents – cationic, anionic and non-ionic surfactants. The structure and morphology of samples of the cellulose fillers and composite films with polymer were analyzed by means of scanning electron microscopy and PXRD diffraction. Thermal parameters of the composite films were characterized by differential scanning calorimetry and thermogravimetric analysis. The tensile strength and elongation at break of the films were evaluated in mechanical tests. The ability to disintegrate of all PLA/ NFC composites under composting conditions was also determined and compared.
纤维素纳米纤维的表面改性对特定聚乳酸/纤维素复合材料机械性能和不可溶性的影响
摘要 聚乳酸/纳米纤维素(NFC)复合膜是通过溶液浇注法生产的。在使用前,用各种类型的表面活性剂(阳离子、阴离子和非离子表面活性剂)对纤维素纤维进行改性。通过扫描电子显微镜和 PXRD 衍射分析了纤维素填料和聚合物复合薄膜样品的结构和形态。通过差示扫描量热法和热重分析对复合薄膜的热参数进行了表征。机械测试评估了薄膜的拉伸强度和断裂伸长率。此外,还测定并比较了所有聚乳酸/ NFC 复合材料在堆肥条件下的分解能力。
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