A. S. Galushko, V. V. Ilyushenkova, Yu. V. Burykina, R. R. Shaidullin, E. O. Pentsak
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引用次数: 0
Abstract
The effect of carbon supports and preparation methods of Pd/C catalysts on leaching of palladium-containing species to the solution upon interaction of a catalyst with a solvent was considered. The leaching of palladium from the support surface into pure solvents was studied by high resolution mass spectrometry. It has been shown that the type of leached palladium species formed in the solution depends not only on the solvent, but also on the method of catalyst deposition on the support and the support nature. It has been found that the use of phosphorus-doped carbon (PC) as a support also results in palladium leaching into solution. In addition, the activity of the catalysts supported on graphite and PC decreased to the same degree both in the Suzuki–Miyaura and Mizoroki–Heck reactions.
期刊介绍：
Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
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