HYDROGEL MEMBRANES BASED ON COPOLYMERS OF 2-HYDROXYETHYL METHACRYLATE WITH POLYVINYLPYRROLIDONE, MODIFIED WITH MONTMORILLONITE AND SILVER NANOPARTICLES

Y. Melnyk, O. Ivanukh, N. Semenyuk, M. B. Kostenko, V. Skorokhoda
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Abstract

Hydrogel membranes based on copolymers of 2-hydroxyethyl methacrylate with polyvinylpyrrolidone, modified with inorganic additives were synthesized. The influence of montmorillonite and silver on the properties of synthesized composite hydrogel membranes was studied. It was established that montmorillonite improves the mechanical properties of membranes, but slightly reduces their permeability. The chemistry of the recovery reaction of silver from its salts using polyvinylpyrrolidone as a reducing agent and stabilizer is proposed. The conducted studies confirmed the prospects of using synthesized hydrogels based on HEMA/PVP copolymers which contain special additives for the marking of biomedical materials with antibacterial properties.
基于 2- 羟乙基甲基丙烯酸酯与聚乙烯吡咯烷酮共聚物的水凝胶膜,并用蒙脱石和纳米银颗粒进行改性
以甲基丙烯酸 2-羟乙基酯与聚乙烯吡咯烷酮的共聚物为基础,用无机添加剂改性合成了水凝胶膜。研究了蒙脱石和银对合成复合水凝胶膜性能的影响。结果表明,蒙脱石改善了膜的机械性能,但略微降低了膜的渗透性。提出了使用聚乙烯吡咯烷酮作为还原剂和稳定剂从银盐中回收银的化学反应。研究证实,基于 HEMA/PVP 共聚物合成的水凝胶含有特殊添加剂,可用于标记具有抗菌特性的生物医学材料。
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