Bis(2,6-di(pyridin-2-yl)pyridin-4-yl)-6,6′-(1,2-diselanediyl)dihexanoate

IF 0.6 Q4 CHEMISTRY, ORGANIC

Molbank Pub Date : 2023-12-20 DOI:10.3390/m1752

E. Popa, A. Andelescu, Valentin Badea, Paula Svera M Ianăşi, Elisabeta I. Szerb

引用次数: 0

Abstract

The present paper describes the preparation and characterization of a new dinuclear ligand based on terpyridine featuring a diselenide unit. This new compound was synthesized in a two-step procedure that first involved the insertion of the diselenide moiety on a carboxylic acid and was followed by a Steglich esterification reaction between the biscarboxylic acid containing the diselenide unit and 2,6-di(pyridin-2-yl)pyridin-4-ol (tpyOH). The title compound was characterized via FT-IR, Raman, NMR (1D and 2D), and UV-Vis spectroscopies and elemental analysis. Emission properties were investigated.

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双(2,6-二(吡啶-2-基)吡啶-4-基)-6,6′-(1,2-二壬二基)二己酸酯。

本文介绍了一种新的双核配体的制备和表征，该配体以具有二硒化单元的三联吡啶为基础。这种新化合物的合成分两步进行，首先将二硒化物插入羧酸中，然后在含有二硒化物单元的双羧酸和 2,6-二(吡啶-2-基)吡啶-4-醇 (tpyOH) 之间进行斯特克里奇酯化反应。通过傅立叶变换红外光谱、拉曼光谱、核磁共振（一维和二维）光谱、紫外-可见光谱和元素分析对标题化合物进行了表征。还对发射特性进行了研究。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)