E. A. Achimova, V. G. Abashkin, A. Yu. Meshalkin, C. S. Losmanschii, V. S. Botnari
{"title":"Polarimetric Features of PEPC Polymer Doped with Photoisomerizable SY3 Azodye Chromophore","authors":"E. A. Achimova, V. G. Abashkin, A. Yu. Meshalkin, C. S. Losmanschii, V. S. Botnari","doi":"10.3103/s1068375523060029","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Photo-induced anisotropy measurements were carried out in thin films of azopolymers PEPC with Solvent Yellow 3, with the concentrations of 10 and 30 wt % of polymers with azo groups in their side-chain. The experimental dependences of the azimuths of the probe beam at the pump beam angles for samples were studied. The photoinduced dependence of the sample birefringence of the probe beam at the incident polarization angle of the pump beam was carried out by the polarimetric method for the studied samples. The geometric phase of anisotropic carbazole-containing azopolymers, in contrast to the dynamic phase, can be measured by the proposed polarimetric method without involving interferometry methods. This is possible because the geometric phase is not controlled by the difference in optical paths but is the result of a change of polarization inside the films due to photoinduced changes in its spatial structure.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Engineering and Applied Electrochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3103/s1068375523060029","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0
Abstract
Photo-induced anisotropy measurements were carried out in thin films of azopolymers PEPC with Solvent Yellow 3, with the concentrations of 10 and 30 wt % of polymers with azo groups in their side-chain. The experimental dependences of the azimuths of the probe beam at the pump beam angles for samples were studied. The photoinduced dependence of the sample birefringence of the probe beam at the incident polarization angle of the pump beam was carried out by the polarimetric method for the studied samples. The geometric phase of anisotropic carbazole-containing azopolymers, in contrast to the dynamic phase, can be measured by the proposed polarimetric method without involving interferometry methods. This is possible because the geometric phase is not controlled by the difference in optical paths but is the result of a change of polarization inside the films due to photoinduced changes in its spatial structure.
期刊介绍：
Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.
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