Hexafluoroisopropylboranes and -Borates

IF 3.1 4区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Inorganics Pub Date : 2023-12-04 DOI:10.3390/inorganics11120471

Ludwig Zapf, Maik Finze

引用次数: 0

Abstract

Novel hexafluoroisopropylboranes (CF3)(CF2H)CFBH2·L and -borate anions [(CF3)(CF2H)CFBH2X]− with Lewis basic heterocyclic ligands L and the anionic substituents X = F− and CN− were obtained. The syntheses were accomplished by substitution reactions of the dimethyl sulfide adduct (CF3)(CF2H)CFBH2·SMe2, which was synthesized on a large scale. The hexafluoroisopropylboranes and -borates were characterized by NMR and vibrational spectroscopy, elemental analysis, and single-crystal X-ray diffraction. In addition, the thermal and electrochemical stabilities were investigated by DSC measurements and cyclic voltammetry and selected experimental data and trends are compared with theoretical ones.

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六氟异丙基硼烷和硼酸盐

得到了新型六氟异丙基硼烷(CF3)(CF2H)CFBH2·L和-硼酸盐阴离子[(CF3)(CF2H)CFBH2X] -，具有路易斯碱杂环配体L和阴离子取代基X = F−和CN−。通过二甲基硫化物加合物(CF3)(CF2H)CFBH2·SMe2的取代反应，实现了该化合物的大规模合成。采用核磁共振、振动光谱、元素分析和单晶x射线衍射对六氟异丙基硼烷和硼酸盐进行了表征。此外，通过DSC测量和循环伏安法研究了其热稳定性和电化学稳定性，并将所选实验数据和趋势与理论数据进行了比较。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Inorganics Chemistry-Inorganic Chemistry

CiteScore

2.80

自引率

10.30%

发文量

193

审稿时长

6 weeks

期刊介绍： Inorganics is an open access journal that covers all aspects of inorganic chemistry research. Topics include but are not limited to: synthesis and characterization of inorganic compounds, complexes and materials structure and bonding in inorganic molecular and solid state compounds spectroscopic, magnetic, physical and chemical properties of inorganic compounds chemical reactivity, physical properties and applications of inorganic compounds and materials mechanisms of inorganic reactions organometallic compounds inorganic cluster chemistry heterogenous and homogeneous catalytic reactions promoted by inorganic compounds thermodynamics and kinetics of significant new and known inorganic compounds supramolecular systems and coordination polymers bio-inorganic chemistry and applications of inorganic compounds in biological systems and medicine environmental and sustainable energy applications of inorganic compounds and materials MD