Advances in selective conversion of carbohydrates into 5-hydroxymethylfurfural

IF 10.7 1区工程技术 Q1 CHEMISTRY, PHYSICAL

Green Energy & Environment Pub Date : 2023-11-22 DOI:10.1016/j.gee.2023.11.005

Jie Liang, Jianchun Jiang, Tingting Cai, Chao Liu, Jun Ye, Xianhai Zeng, Kui Wang

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Abstract

Converting carbohydrates into 5-hydroxymethylfurfural (5-HMF) is an attractive and promising route for value-added utilization of agricultural and forestry biomass resource. As an important platform compound, 5-HMF possesses high active furan structure with hydroxymethyl and aldehyde group for production of various bio-chemicals and materials, meanwhile, which suffer from low stability and poor yield during the industrial biorefinery process. Hence, selective production of 5-HMF with high-yield and low-cost has attracted extensive attention from scientific and industrial researchers. This review sorted and described the latest advanced research on solvent and catalyst system, as well as energy field effect for production of 5-HMF with different feedstock in detail, emphatically discussing the solvent effect and its synergistic effect with other aspects. Besides, the future prospects and challenges for production of 5-HMF from carbohydrates were also presented, which provide a profound insight into industrial 5-HMF process with economic and environmental feature.

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碳水化合物选择性转化为5-羟甲基糠醛的研究进展

将碳水化合物转化为5-羟甲基糠醛(5-HMF)是农林生物质资源增值利用的一条有吸引力和前景的途径。5-HMF是一种重要的平台化合物，具有高活性的呋喃结构，具有羟甲基和醛基团，可用于生产各种生物化工和材料，但在工业生物炼制过程中存在稳定性低、产率差的问题。因此，高产低成本的5-羟甲基糠醛的选择性生产受到了科学和工业研究人员的广泛关注。本文对不同原料制备5-羟甲基糠醛的溶剂和催化剂体系以及能量场效应的最新研究进展进行了详细的梳理和描述，重点讨论了溶剂效应及其与其他方面的协同效应。展望了碳水化合物制备5-羟甲基糠醛的未来前景和面临的挑战，对具有经济性和环保性的工业5-羟甲基糠醛工艺提供了深刻的见解。

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来源期刊

Green Energy & Environment Energy-Renewable Energy, Sustainability and the Environment

CiteScore

16.80

自引率

3.80%

发文量

332

审稿时长

12 days

期刊介绍： Green Energy & Environment (GEE) is an internationally recognized journal that undergoes a rigorous peer-review process. It focuses on interdisciplinary research related to green energy and the environment, covering a wide range of topics including biofuel and bioenergy, energy storage and networks, catalysis for sustainable processes, and materials for energy and the environment. GEE has a broad scope and encourages the submission of original and innovative research in both fundamental and engineering fields. Additionally, GEE serves as a platform for discussions, summaries, reviews, and previews of the impact of green energy on the eco-environment.