{"title":"Effect of Collector Physisorption on Flotation of Galena with Xanthate and Pb2+","authors":"S. A. Kondrat’ev, I. A. Konovalov","doi":"10.1134/s1062739123040130","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The authors propose the galena flotation mechanism based on the joint work of chemisorbed collector and physisorbed lead xanthate in molecular form. It is proved experimentally that the products of interaction between xanthate and lead ions possess surface activity dependent on the concentration ratio and on solution pH. In alkaline range, they spread over the gas–water interface and can remove water from the interlayer between a mineral particle and a gas bubble. In sub-acid medium and at the increased mole ratio of lead ions to xanthate anions, the spreading velocity of the interaction products decreases. The physisorption mechanism of the collector has disclosed the causes of high floatability of galena in the alkaline range of pH and the decreased floatability in the sub-acid domain.</p>","PeriodicalId":16358,"journal":{"name":"Journal of Mining Science","volume":"21 2","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Mining Science","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1134/s1062739123040130","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MINING & MINERAL PROCESSING","Score":null,"Total":0}
引用次数: 0
Abstract
The authors propose the galena flotation mechanism based on the joint work of chemisorbed collector and physisorbed lead xanthate in molecular form. It is proved experimentally that the products of interaction between xanthate and lead ions possess surface activity dependent on the concentration ratio and on solution pH. In alkaline range, they spread over the gas–water interface and can remove water from the interlayer between a mineral particle and a gas bubble. In sub-acid medium and at the increased mole ratio of lead ions to xanthate anions, the spreading velocity of the interaction products decreases. The physisorption mechanism of the collector has disclosed the causes of high floatability of galena in the alkaline range of pH and the decreased floatability in the sub-acid domain.
期刊介绍：
The Journal reflects the current trends of development in fundamental and applied mining sciences. It publishes original articles on geomechanics and geoinformation science, investigation of relationships between global geodynamic processes and man-induced disasters, physical and mathematical modeling of rheological and wave processes in multiphase structural geological media, rock failure, analysis and synthesis of mechanisms, automatic machines, and robots, science of mining machines, creation of resource-saving and ecologically safe technologies of mineral mining, mine aerology and mine thermal physics, coal seam degassing, mechanisms for origination of spontaneous fires and methods for their extinction, mineral dressing, and bowel exploitation.
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