Generation of tert-butyl-λ5-phosphanedione and its chemical properties

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2022-01-01 DOI:10.1080/10426507.2022.2031197

Oleg Kolodiazhnyi , Olga Kolodiazhna , Evgen Grishkun , Anastasy Kolodiazhna , Sergei Sheiko

引用次数: 0

Abstract

Tert-butyl-λ⁵-phosphanedione was generated by flash vacuum thermolysis (FVT) of trimethylsilyl tert-butyl phosphonohalidates. The structure of tert-butyl-λ⁵-phosphanedione was confirmed by chemical reactions. Tert-butyl-λ⁵-phosphandione readily undergoes trimerization, enters into the [2 + 3] - cycloaddition reaction with 2-phenyloxirane and adds alcohols.

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叔丁基-λ5-磷二酮的生成及其化学性质

以三甲基硅基膦酸叔丁基为原料，采用闪蒸真空热裂解法制备了叔丁基-λ5-磷二酮。通过化学反应证实了叔丁基-λ5-磷二酮的结构。叔丁基-λ5-磷二酮容易发生三聚反应，与2-苯基氯烷发生[2 + 3]-环加成反应，并加入醇。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.