Advanced tetra amino (ATA-100) cobalt(II) phthalocyanine-based metallo-covalent organic polymer for sensitively detecting volatile organic compounds

IF 1.3 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Turkish Journal of Chemistry Pub Date : 2023-10-31 DOI:10.55730/1300-0527.3600

GÜNSELİ GÜNEY, GÜLAY ALTINDEMİR KAPLAN, CİHAT TAŞALTIN, İLKE GÜROL

引用次数: 0

Abstract

The synthesis and characterization of a novel covalent organic polymer cobalt (II) phthalocyanine (ATA-100) including tetra amino group is described for the first time. This covalent organic polymer (COP) is characterized by FTIR, TGA, RAMAN, PXRD, and SEM-EDS. The developed sensor is tested for acetone, ethyl butyrate, n-hexane, chloroform, and n-butyraldehyde in a range of 80-10,900 ppm. ATA-100 showed the highest sensitivity for ethyl butyrate. The results have confirmed the possibility of utilizing ATA-100 COP-based surface acoustic wave (SAW) sensors for a wide variety of applications, including indoor air quality and environmental monitoring of volatile organic compounds (VOCs).

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先进的四氨基(ATA-100)钴(II)酞菁基金属共价有机聚合物，用于灵敏检测挥发性有机化合物

首次合成了含四氨基的新型共价有机聚合物酞菁钴(ATA-100)。通过FTIR, TGA, RAMAN, PXRD和SEM-EDS对该共价有机聚合物(COP)进行了表征。开发的传感器在80-10,900 ppm范围内测试丙酮，丁酸乙酯，正己烷，氯仿和正丁醛。ATA-100对丁酸乙酯的灵敏度最高。研究结果证实，ATA-100型表面声波(SAW)传感器可广泛应用于室内空气质量和挥发性有机化合物(VOCs)环境监测等领域。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Turkish Journal of Chemistry 化学-工程：化工

CiteScore

2.40

自引率

7.10%

发文量

审稿时长

3 months

期刊介绍： The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.