Anthony U AWODE, Sunday ELAİGWU, Akeem A OLADİPO, Osman YILMAZ, Mustafa GAZİ
{"title":"Removal of Methylene Blue Dye from Aqueous Solution Using Trichlorovinylsilane Chitosan–g–polyacrylamide Hydrogel","authors":"Anthony U AWODE, Sunday ELAİGWU, Akeem A OLADİPO, Osman YILMAZ, Mustafa GAZİ","doi":"10.18596/jotcsa.1292604","DOIUrl":null,"url":null,"abstract":"A new hydrogel based on vinylsilane-chitosan and acrylamide was synthesized as VSi-CTS-g-PAAm and was used to remove methylene blue (MB) from aqueous solution using batch adsorption technique. The VSi-CTS-PAAm hydrogel interacted with methylene blue (MB) dye solution at different mass-liquid ratios, pH, and temperature. The amount of MB dye removal was estimated using a UV-Vis spectrophotometer at an optical density of λmax= 665 nm. The MB dye removal was most effective at pH 12, with about 98 % removal at 50 °C. The study's findings also indicated that the equilibrium data exhibited the highest degree of conformity with the Langmuir isotherm model. Additionally, the adsorption process adhered to the pseudo-second-order kinetics and was characterized as endothermic. Therefore, our study suggests that the utilization of prepared materials may have potential advantages in treating wastewater containing dyes.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":"67 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Turkish Chemical Society, Section A: Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18596/jotcsa.1292604","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Chemistry","Score":null,"Total":0}
引用次数: 0
Abstract
A new hydrogel based on vinylsilane-chitosan and acrylamide was synthesized as VSi-CTS-g-PAAm and was used to remove methylene blue (MB) from aqueous solution using batch adsorption technique. The VSi-CTS-PAAm hydrogel interacted with methylene blue (MB) dye solution at different mass-liquid ratios, pH, and temperature. The amount of MB dye removal was estimated using a UV-Vis spectrophotometer at an optical density of λmax= 665 nm. The MB dye removal was most effective at pH 12, with about 98 % removal at 50 °C. The study's findings also indicated that the equilibrium data exhibited the highest degree of conformity with the Langmuir isotherm model. Additionally, the adsorption process adhered to the pseudo-second-order kinetics and was characterized as endothermic. Therefore, our study suggests that the utilization of prepared materials may have potential advantages in treating wastewater containing dyes.