Enrichment characteristics and its geological significance of dispersed elements within sulfide minerals from the Ⅵ ore belt in the Maoping Pb-Zn deposit, Yunnan Province, China

IF 1.7 3区地球科学 Q2 GEOLOGY

岩石学报 Pub Date : 2023-01-01 DOI:10.18654/1000-0569/2023.10.08

HE Ye, ZHOU GaoMing, ZHONG Hua, CHENG Yong, YUE ZhengPeng, LIU HeSong, ZHOU JiaXi

{"title":"Enrichment characteristics and its geological significance of dispersed elements within sulfide minerals from the Ⅵ ore belt in the Maoping Pb-Zn deposit, Yunnan Province, China","authors":"HE Ye, ZHOU GaoMing, ZHONG Hua, CHENG Yong, YUE ZhengPeng, LIU HeSong, ZHOU JiaXi","doi":"10.18654/1000-0569/2023.10.08","DOIUrl":null,"url":null,"abstract":"作为华南大面积低温成矿域的重要组成部分,川滇黔铅锌矿集区是我国重要的铅锌银等资源基地之一,同时该矿集区也是Ge、Cd、Ga和In等稀散元素的超常富集区域。毛坪矿床是该矿集区内第二大铅锌矿床,累计探明铅锌金属储量超过3Mt (Pb+Zn平均品位≥18%),锗(Ge)保有储量182t。本文以新发现的Ⅵ矿带(铅锌金属已探明储量≥60万t,Pb+Zn平均品位≥20%)为研究对象,利用LA-ICPMS对主要矿石矿物闪锌矿和黄铁矿进行了微区原位微量元素组成和Mapping分析。研究结果显示Ⅵ矿带闪锌矿普遍富集Ge(最高580×10-6,均值81.1×10-6)、Cd(最高3486×10-6,均值1613×10-6)和Ga(最高190×10-6,均值44.4×10-6);黄铁矿普遍富集Mn、As、Pb、Cu、Ag和Sb。与Ⅰ和Ⅱ号矿带闪锌矿相比,Ⅵ号矿带闪锌矿更富集Ge和Ga。闪锌矿中Fe和Pb以类质同象为主,偶见黄铁矿和方铅矿显微包体;Cu、Ge、Ag和As赋存形式主要为类质同象,替代方式为Ge4++2(Cu+, Ag+, As+)↔3Zn2+;Cd以类质同象方式赋存为主,替代机制为Cd2+↔Zn2+;Ga和In可能主要以类质同象方式存在。黄铁矿中Pb和Mn主要以方铅矿和碳酸盐矿物显微包体为主;Cu、As和Sb以类质同象形式存在于黄铁矿中;Ag和Zn可能以独立矿物形式赋存;Co和Ni以类质同象方式替代Fe进入黄铁矿晶格中,替代方式为Ni2++Co2+↔2Fe2+。毛坪矿床新发现Ⅵ矿带硫化物相比典型MVT矿床硫化物具有不同的In和Ge含量以及Cd/Fe比值,结合矿床地质特征和其他证据,表明毛坪矿床成因类型特殊,有别于经典MVT铅锌矿床,属于川滇黔型铅锌矿床。","PeriodicalId":7075,"journal":{"name":"岩石学报","volume":"33 1","pages":"0"},"PeriodicalIF":1.7000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"岩石学报","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18654/1000-0569/2023.10.08","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOLOGY","Score":null,"Total":0}

引用次数: 0

Abstract

作为华南大面积低温成矿域的重要组成部分,川滇黔铅锌矿集区是我国重要的铅锌银等资源基地之一,同时该矿集区也是Ge、Cd、Ga和In等稀散元素的超常富集区域。毛坪矿床是该矿集区内第二大铅锌矿床,累计探明铅锌金属储量超过3Mt (Pb+Zn平均品位≥18%),锗(Ge)保有储量182t。本文以新发现的Ⅵ矿带(铅锌金属已探明储量≥60万t,Pb+Zn平均品位≥20%)为研究对象,利用LA-ICPMS对主要矿石矿物闪锌矿和黄铁矿进行了微区原位微量元素组成和Mapping分析。研究结果显示Ⅵ矿带闪锌矿普遍富集Ge(最高580×10^-6,均值81.1×10^-6)、Cd(最高3486×10^-6,均值1613×10^-6)和Ga(最高190×10^-6,均值44.4×10^-6);黄铁矿普遍富集Mn、As、Pb、Cu、Ag和Sb。与Ⅰ和Ⅱ号矿带闪锌矿相比,Ⅵ号矿带闪锌矿更富集Ge和Ga。闪锌矿中Fe和Pb以类质同象为主,偶见黄铁矿和方铅矿显微包体;Cu、Ge、Ag和As赋存形式主要为类质同象,替代方式为Ge⁴⁺+2(Cu⁺, Ag⁺, As⁺)↔3Zn²⁺;Cd以类质同象方式赋存为主,替代机制为Cd²⁺↔Zn²⁺;Ga和In可能主要以类质同象方式存在。黄铁矿中Pb和Mn主要以方铅矿和碳酸盐矿物显微包体为主;Cu、As和Sb以类质同象形式存在于黄铁矿中;Ag和Zn可能以独立矿物形式赋存;Co和Ni以类质同象方式替代Fe进入黄铁矿晶格中,替代方式为Ni²⁺+Co²⁺↔2Fe²⁺。毛坪矿床新发现Ⅵ矿带硫化物相比典型MVT矿床硫化物具有不同的In和Ge含量以及Cd/Fe比值,结合矿床地质特征和其他证据,表明毛坪矿床成因类型特殊,有别于经典MVT铅锌矿床,属于川滇黔型铅锌矿床。

查看原文本刊更多论文

云南茂坪铅锌矿Ⅵ矿带硫化物矿物中分散元素富集特征及其地质意义

作为华南大面积低温成矿域的重要组成部分,川滇黔铅锌矿集区是我国重要的铅锌银等资源基地之一,同时该矿集区也是Ge、Cd、Ga和In等稀散元素的超常富集区域。毛坪矿床是该矿集区内第二大铅锌矿床,累计探明铅锌金属储量超过3Mt (Pb+Zn平均品位≥18%),锗(Ge)保有储量182t。本文以新发现的Ⅵ矿带(铅锌金属已探明储量≥60万t,Pb+Zn平均品位≥20%)为研究对象,利用LA-ICPMS对主要矿石矿物闪锌矿和黄铁矿进行了微区原位微量元素组成和Mapping分析。研究结果显示Ⅵ矿带闪锌矿普遍富集Ge(最高580×10-6,均值81.1×10-6)、Cd(最高3486×10-6,均值1613×10-6)和Ga(最高190×10-6,均值44.4×10-6);黄铁矿普遍富集Mn、As、Pb、Cu、Ag和Sb。与Ⅰ和Ⅱ号矿带闪锌矿相比,Ⅵ号矿带闪锌矿更富集Ge和Ga。闪锌矿中Fe和Pb以类质同象为主,偶见黄铁矿和方铅矿显微包体;Cu、Ge、Ag和As赋存形式主要为类质同象,替代方式为Ge4++2(Cu+, Ag+, As+)↔3Zn2+;Cd以类质同象方式赋存为主,替代机制为Cd2+↔Zn2+;Ga和In可能主要以类质同象方式存在。黄铁矿中Pb和Mn主要以方铅矿和碳酸盐矿物显微包体为主;Cu、As和Sb以类质同象形式存在于黄铁矿中;Ag和Zn可能以独立矿物形式赋存;Co和Ni以类质同象方式替代Fe进入黄铁矿晶格中,替代方式为Ni2++Co2+↔2Fe2+。毛坪矿床新发现Ⅵ矿带硫化物相比典型MVT矿床硫化物具有不同的In和Ge含量以及Cd/Fe比值,结合矿床地质特征和其他证据,表明毛坪矿床成因类型特殊,有别于经典MVT铅锌矿床,属于川滇黔型铅锌矿床。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

岩石学报 Earth and Planetary Sciences-Geochemistry and Petrology

CiteScore

3.60

自引率

22.20%

发文量

5997

审稿时长

6 months

期刊介绍： Acta Petrologica Sinica is an academic journal under the supervision of the Chinese Academy of Sciences and sponsored by the Chinese Society of Mineralogy, Petrology and Geochemistry and the Institute of Geology and Geophysics of the Chinese Academy of Sciences. The journal's publishing policy is to adhere to innovation, comprehensiveness, cutting-edge and orientation, advocate diversity and multi-school, rely on and unite the vast number of geoscientists across the country, explore the mysteries of nature, carry out extensive and in-depth basic theoretical research, promote the research and development of the field of earth science in my country, publish high-level scientific research results, and cultivate and train a large number of geoscientific research talents for my country. Acta Petrologica Sinica mainly reports on various disciplines related to the basic theory of petrology, including important basic theories and applied research results in magmatic petrology, metamorphic petrology, sedimentary petrology, petrology geotectonics, rock isotope chronology and isotope geochemistry, rock mineralization, and rock-forming mineralogy. At the same time, the journal also publishes review articles, problem discussions, academic trends and book reviews.