Reinforcing effect of MWCNT derivatives on glass/epoxy and carbon/epoxy composites perpendicular to the fiber direction

Abstract

In the current study, the nano-composites of unidirectional carbon and glass fiber reinforced-epoxy resin with multi-walled carbon nanotubes (MWCNTs) were separately prepared by hand lay-up and hot pressing of fiber epoxy prepregs. Three types of MWCNT derivatives (parent-CNT, low carboxylated CNT (LCCNT) and higher carboxylated CNT (HCCNT)) were dispersed into the epoxy resin/fiber composites. The improved mechanical properties observed in the three component composites could be attributed to the uniform dispersion of CNTs in epoxy/ fiber matrices, nanosize of the additives and the improved interfacial interactions between the composite components. The COOH functional groups could also be effective in the increase of mechanical traits because they induce the amphiphilic nature into CNTs for better dispersion and to generate the better glass fiber/epoxy (E/G) and carbon fiber/epoxy (E/C) interactions. HCCNT led to the best mechanical properties among all the samples due to its higher carboxyl content. HCCNT also changed the curing peak of epoxy in DSC and improved its thermal stability. For instance, the final residual mass for E/HCCNT was 15.4% at 600 °C compared to 13.92% for the pure epoxy while the values of 17.55 and 16.48% were observed at 500 °C for E/HCCNT and epoxy, respectively. The observed effect of COOH functionality on the void formation within the composite and on the better CNT dispersion in the matrix can be considered as an important observation for investigating the E/C/CNTs nanocomposites.