Water in Fullerenes

IF 3.3 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Bulletin of the Chemical Society of Japan Pub Date : 2023-09-15 DOI:10.1246/bcsj.20230135

Yoshifumi Hashikawa, Yasujiro Murata

引用次数: 0

Abstract

A water molecule fixed within [60]fullerene is the simplest form of water available in meatspace. It was first artificially made by us in 2011. Since then, anomalies of water molecules free from any hydrogen-bonding have been discovered in succession. In this account, we summarize the research progress in the past decade from the aspect of synthesis, derivatization, and reactivity of fullerenes with water inside as well as their quantum and classical dynamics. A single water molecule trapped within fullerene cages has been found to modulate the chemical and physical nature of exohedral cages as well as to exhibit anomalous quantum spin conversion. In this account, we discuss the synthesis, modulated exohedral properties, ortho–para conversion, and classical dynamics of water in fullerenes.

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富勒烯中的水

固定在富勒烯内的水分子[60]是肉空间中最简单的水形式。它是我们在2011年首次人工制作的。从那以后，陆续发现了没有氢键的水分子的异常现象。本文从富勒烯的合成、衍生化、含水反应性、量子动力学和经典动力学等方面综述了近十年来富勒烯的研究进展。被困在富勒烯笼中的单个水分子被发现可以调节外面体笼的化学和物理性质，并表现出反常的量子自旋转换。在这篇文章中，我们讨论了富勒烯中水的合成、调制的外面体性质、邻对位转换和经典动力学。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Bulletin of the Chemical Society of Japan 化学-化学综合

CiteScore

6.40

自引率

5.00%

发文量

194

审稿时长

3-8 weeks

期刊介绍： The Bulletin of the Chemical Society of Japan (BCSJ) is devoted to the publication of scientific research papers in the fields of Theoretical and Physical Chemistry, Analytical and Inorganic Chemistry, Organic and Biological Chemistry, and Applied and Materials Chemistry. BCSJ appears as a monthly journal online and in advance with three kinds of papers (Accounts, Articles, and Short Articles) describing original research. The purpose of BCSJ is to select and publish the most important papers with the broadest significance to the chemistry community in general. The Chemical Society of Japan hopes all visitors will notice the usefulness of our journal and the abundance of topics, and welcomes more submissions from scientists all over the world.