Zhiqian Cao, Guangyao Hu, Weixing Feng, Jie Ru, Yujin Li
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引用次数: 0
Abstract
Two-dimensional (2D) transition metal carbonitrides/nitrides (MXene) materials have proven to be promising alternatives as novel capacitor-type electrodes for aqueous Zn-ion hybrid microsupercapacitors (ZHMSCs). However, during self-assembly processes, serious restacking between 2D MXene nanosheets induced by strong van der Waals forces makes ion transport channels narrow within the compact MXene film electrodes, which would result in poor energy output of ZHMSCs. Herein, interlayer transport channel engineering is designed by intercalating bacterial cellulose (BC) between MXene interlayers to develop MXene/BC electrodes with fast ion transport channels in contrast to pure MXene electrodes. Benefiting from fast anion intercalation/deintercalation on MXene/BC capacitor-type cathode and reversible Zn stripping/plating on Zn foil anode, the fabricated ZHMSCs exhibit wide working potential windows (1.36 V), high areal capacitance (404 mF cm−2), and landmark areal energy density (94 µWh cm−2 at 1 mA cm−2). The areal capacitance and energy density of the developed ZHMSCs are much higher than those of the ZHMSCs based on pure MXene capacitor-type cathode (239 mF cm−2/57 µWh cm−2 at 1 mA cm−2). Besides, the developed ZHMSCs can perform more than 10,000 cycles, showing outstanding capacity retention. In general, our work provides a novel strategy to break through the performance bottlenecks afflicting MXene-based ZHMSCs.
二维(2D)过渡金属碳氮化物/氮化物(MXene)材料已被证明是一种很有前途的替代材料,可作为新型电容器型电极用于水性锌离子混合微超级电容器(ZHMSCs)。然而,在自组装过程中,由强范德华力引起的二维MXene纳米片之间严重的再堆积使得紧凑的MXene薄膜电极内的离子传输通道变窄,这将导致ZHMSCs的能量输出较差。本文设计了层间传输通道工程,通过在MXene层间嵌入细菌纤维素(BC),开发出与纯MXene电极相比具有快速离子传输通道的MXene/BC电极。得益于在MXene/BC电容器型阴极上的快速阴离子插入/脱嵌和在Zn箔阳极上的可逆Zn剥离/镀,制备的ZHMSCs具有宽的工作电位窗口(1.36 V),高的面电容(404 mF cm−2)和具有划时代意义的面能量密度(1 mA cm−2时94µWh cm−2)。该材料的面电容和能量密度均明显高于纯MXene电容器型阴极材料的面电容和能量密度(1 mA cm - 2时为239 mF cm - 2 /57µWh cm - 2)。此外,所开发的ZHMSCs可以进行超过10,000次循环,具有出色的容量保持能力。总的来说,我们的工作提供了一种新的策略来突破困扰基于MXene的ZHMSCs的性能瓶颈。