Kinetics of the Water Release of Hygroscopic Acrylamide Gel Embedded in Calcium Chloride by Thermogravimetric Analysis

Nasrollah Hamidi, India Williams, Hushmand Hamidi
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Abstract

Poly (acrylamide) gel was synthesized by radical polymerization of acrylamide and N, N'-methylene-bisacrylamide in the presence of benzoyl peroxide and carbon nanotubes. The dry product was saturated with calcium chloride and prepared for water absorption and desorption. The kinetics of water desorption of poly (acrylamide) gel embedded with hygroscopic calcium chloride (DHG), was studied from thermograms data of thermogravimetric analysis (TGA). DHG captures vapor from the environment and releases it as fresh water; it can be used as the condenser to build atmospheric water generators (AWGs) to alleviate the freshwater stress rusting from innovative activities such as industrial, agricultural, rural, and defense endeavors. The kinetics parameters of the synthesized DHG showed that it absorbed environmental vapor at room temperature and released water below its boiling point (40 to 90 °C), temperatures achievable under sunlight via the photothermal effect.
用热重法分析包埋在氯化钙中的吸湿性丙烯酰胺凝胶的释水动力学
在过氧化苯甲酰和碳纳米管的存在下,用丙烯酰胺和N, N′-亚甲基双丙烯酰胺自由基聚合法制备了聚丙烯酰胺凝胶。用氯化钙饱和干燥产物,制备吸水解吸。利用热重分析(TGA)的热图数据,研究了包埋氯化钙(DHG)的聚丙烯酰胺凝胶解吸水动力学。DHG从环境中捕获蒸汽并将其作为淡水释放;它可以用作冷凝器来建造大气水发生器(awg),以减轻工业、农业、农村和国防等创新活动造成的淡水压力生锈。合成的DHG的动力学参数表明,它在室温下吸收环境蒸汽,并释放低于其沸点(40 ~ 90℃)的水,这是在阳光下通过光热效应可以达到的温度。
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