{"title":"Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation","authors":"Vitalii Vashchynskyi, Olena Okhay, Tetiana Boychuk","doi":"10.3390/c9040093","DOIUrl":null,"url":null,"abstract":"The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO3 and annealing at 450 °C led to an increase in surface area up to 1300 m2/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production.","PeriodicalId":9397,"journal":{"name":"C","volume":"76 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"C","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/c9040093","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO3 and annealing at 450 °C led to an increase in surface area up to 1300 m2/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production.