EFFECT OF POLYMER RATIO ON THERMAL PROPERTIES OF POLYHYDROXYBUTYRATE/POLYHYDROXYHEXANOATE

Nguyen Hong Thanh, Roman O. Olekhnovich, Mayya V. Uspenskaya, Vera E. Sitnikova, Collins Ngoe Elangwe
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Abstract

In this study, a PHB nanofiber mat with various concentrations of PHH was successfully prepared by the electrospinning method. The morphology of the PHB nanofibers was observed by the microscope. Fourier transform infrared spectroscopy (FTIR) was used to evaluate the characteristic groups for the PHB sample with various concentrations of PHH in pellet and nanofibers mat form. DSC analysis was used to investigate the change in melting point and the crystallization temperature of PHB with various concentrations of PHH. TG and DTG were used to test the decomposition temperature as well as the mass loss of PHB pellet and PHB nanofiber mat with various concentrations of PHH. The DSC, DTA, and TGA thermal analysis results showed that the melting, glass transition, decomposition initiation, and decomposition termination temperatures decreased with increasing PHH concentrations
聚合物配比对聚羟基丁酸酯/聚羟基己酸酯热性能的影响
本研究采用静电纺丝法制备了不同浓度PHH的PHB纳米纤维垫。用显微镜观察了PHB纳米纤维的形貌。采用傅里叶变换红外光谱(FTIR)对不同浓度PHH颗粒和纳米纤维席形式的PHB样品的特征基团进行了评价。采用DSC分析研究了PHB的熔点和结晶温度随PHH浓度的变化。采用热重法(TG)和差热重法(DTG)测定了PHB球团和PHB纳米纤维垫在不同浓度PHH下的分解温度和质量损失。DSC、DTA和TGA热分析结果表明,随着PHH浓度的增加,熔融温度、玻璃化转变温度、分解起始温度和分解终止温度均降低
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