Fluid Inclusions in Glendonite Found on Japan Sea Continental Slope: Pyrolysis-free Gas Chromatography-mass Spectrometry Analysis Research Results

Abstract

For the first time, original results concerning the composition of fluids extracted from glendonite found in Japan (East) Sea continental slope bottom sediment have been obtained. We used the one-act shock-destructive extraction of volatile components from fluid inclusions and made their pyrolysis-free gas chromatography-mass spectrometry analysis, which, despite the limited amount of analytical data, are of scientific and practical interest. According to the data obtained, the fluids in glendonite represent a complex multicomponent mineral-forming system. In addition to water and carbon dioxide, representatives of 13 homologous series of organic compounds were found in the studied fluid inclusions. These include oxygen-free aliphatic and cyclic hydrocarbons (paraffins, olefins, cyclic alkanes and alkenes, arenes, polycyclic aromatic hydrocarbons-PAHs), oxygenated hydrocarbons (alcohols, ethers and esters, furans, aldehydes, ketones, carboxylic acids), nitrogen-, sulfur-, halogenated compounds. An oxidized water-carbon dioxide fluid with a reduced content of hydrocarbons and S–N–F-containing compounds 0.8 rel % is preserved in glendonite.