Fabrication of super-hydrophobic duo-structures

X. Zhang, F. Zhang, Y. Jiang, Y. Y. Wang, Z. Shi, C. Peng
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引用次数: 2

Abstract

Recently, super-hydrophobicity has attracted increasing attention due to its huge potential in the practical applications. In this paper, we have presented a duo-structure of the combination of micro-dot-matrix and nano-candle-soot. Polydimethylsiloxane (PDMS) was used as a combination layer between the dot-matrix and the soot particles. Firstly, a period of 9-μm dot-matrix was easily fabricated on the K9 glass using the most simple and mature photolithography process. Secondly, the dot-matrix surface was coated by a thin film of PDMS (elastomer: hardener=10:1) which was diluted by methylbenzene at the volume ratio of 1:8. Thirdly, we held the PDMS modified surface over a candle flame to deposit a soot layer and followed by a gentle water-risen to remove the non-adhered particles. At last, the samples were baked at 85℃ for 2 hours and then the duo-structure surface with both micro-size dot-matrix and nano-size soot particles was obtained. The SEM indicated this novel surface morphology was quite like a lotus leaf of the well-know micro-nano-binary structures. As a result, the contact angle meter demonstrated such surface exhibited a perfect super-hydrophobicity with water contact angle of 153° and sliding angle of 3°. Besides, just listed as above, the fabrication process for our structure was quite more easy, smart and low-cost compared with the other production technique for super-hydrophobic surfaces such as the phase separation method, electrochemical deposition and chemical vapor deposition etc. Hence, this super-hydrophobic duo-structure reported in this letter was a great promising candidate for a wide and rapid commercialization in the future.
超疏水双结构的制备
近年来,超疏水性因其在实际应用中的巨大潜力而受到越来越多的关注。本文提出了一种由微点阵和纳米蜡烛烟灰组成的二元结构。采用聚二甲基硅氧烷(PDMS)作为点阵与烟尘颗粒之间的结合层。首先,采用最简单、最成熟的光刻工艺,在K9玻璃上制备了周期为9 μm的点阵;其次,在点阵表面涂上一层PDMS(弹性体:硬化剂=10:1)薄膜,以1:8体积比的甲苯稀释PDMS薄膜。第三,我们在蜡烛火焰上放置PDMS修饰的表面以沉积烟灰层,然后用温和的水来去除不粘附的颗粒。最后,将样品在85℃下焙烧2小时,得到了微尺度点阵和纳米尺度烟尘颗粒的双结构表面。扫描电镜显示,这种新型的表面形态很像众所周知的微纳二元结构的荷叶。接触角测量结果表明,该表面具有完美的超疏水性,水接触角为153°,滑动角为3°。此外,如上所述,与相分离法、电化学沉积法、化学气相沉积法等其他超疏水表面的生产技术相比,我们的结构的制造过程更加简单、智能和低成本。因此,这封信中报道的这种超疏水双结构在未来具有广泛而快速的商业化前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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