Progress in the Synthesis of Germanium Chalcogenides Containing Silver

Cui Can, Baiyin Menghe, Guoxin Jia, Teri Gele
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引用次数: 0

Abstract

: In recent years, germanium containing sulfur compounds have attracted much attention due to their complex structural properties and potential applications, and have been widely used in nonlinear optics, molecular sieve, ion exchange and so on. Group 11 elements Ag have been proved to be successful multifunctional elements often used for synthesis, because they have rich coordination modes and electrothermal properties. In addition, they also enhance the metalophilic interaction, overcome the repulsive force between cationic metal centers, and more easily enter the skeleton to form new materials with unique topological structures. The potential applications of these materials extend beyond traditional fields. The synthesis and structure of germanium chalcogenides containing transition metal silver are reviewed in this paper. Various coordination modes of structural units in the basic framework of transition metal silver and germanium sulfide compounds, synthesis methods, structural characteristics and applications of different germanium sulfide compounds containing transition metal silver are summarized. And the synthesis of germanium sulfide compounds containing silver when alkali metals, transition metal complexes, organic amines are used as structure guide agent.
含银硫属锗的合成研究进展
近年来,含锗硫化合物因其复杂的结构性质和潜在的应用前景而备受关注,在非线性光学、分子筛、离子交换等领域得到了广泛的应用。十一族元素银由于具有丰富的配位模式和电热性质,已被证明是常用的成功的多功能合成元素。此外,它们还增强了亲金属相互作用,克服了阳离子金属中心之间的排斥力,更容易进入骨架,形成具有独特拓扑结构的新材料。这些材料的潜在应用范围超出了传统领域。本文综述了含过渡金属银的硫族锗的合成及其结构。综述了过渡金属银与硫化锗化合物基本骨架中结构单元的各种配位模式、不同含过渡金属银的硫化锗化合物的合成方法、结构特点及应用。并在合成含银硫化锗化合物时采用碱金属、过渡金属配合物、有机胺等作为结构引导剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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