Design of Novel Photoanode based on Au-NPs embedded TiO2 Photoanode for Dye-Sensitized Solar Cells Application

B. Shougaijam, Salam Surjit Singh
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Abstract

With the increase in demand of economic, ecofriendly, and portable solar cell, Dye-Sensitized Solar Cells (DSSCs) is a promising candidate which may give the above demands. The main objective of this research work is to adopt Glancing Angle Deposition (GLAD) technique for developing novel Gold (Au) nanoparticles assisted between vertically aligned TiO2 nanowires photoanode on glass substrates for DSSCs application. The structural and morphology analysis shows the successful deposition of Au nanoparticles (Au-NPs) embedded between vertically aligned TiO2 nanowire. Further, the TEM analysis confirms that Au-NPs are embedded at the middle of the nanowires. It is interesting to observe a broad photon absorption in the UV and visible region due to combining effects of Surface Plasmon Resonance of metal NPs and scattering of light between NWs. This controllable deposition technique for metal NP embedded NWs may be suitable for designing photoanode for DSSCs applications with enhance efficiency.
基于Au-NPs包埋TiO2光阳极的染料敏化太阳能电池光阳极设计
随着人们对经济、环保和便携太阳能电池需求的增加,染料敏化太阳能电池(DSSCs)有望满足上述需求。本研究的主要目的是利用掠角沉积(GLAD)技术在垂直排列的二氧化钛纳米线光阳极之间制备新型的金(Au)纳米粒子,用于DSSCs的应用。结构和形貌分析表明,在垂直排列的TiO2纳米线之间成功沉积了金纳米粒子(Au- nps)。此外,TEM分析证实Au-NPs嵌入在纳米线的中间。由于金属NPs的表面等离子体共振和NWs之间的光散射的共同作用,在紫外和可见光区观察到广泛的光子吸收是有趣的。这种可控制的金属NP嵌入NWs沉积技术可用于设计DSSCs应用的光阳极,提高效率。
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