Study on the Pyrolysis Characterization of Rice Husk Var in CO2/N2 Atmosphere

Bingyan Hou, Zeguo Liu, Jian Zhao, Chunliang Li
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Abstract

The pyrolysis characteristics of rice husk under CO2/N2 atmosphere were studied mainly by thermogravimetric differential thermal analysis, in which the pyrolysis kinetics of rice husk under CO2/N2 atmosphere was analyzed by Coats Redfern method, and the pyrolysis products of rice husk under CO2/N2 atmosphere were studied by a two-stage fixed-bed pyrolysis reactor. The results showed that the fitted curves had good correlation in the main pyrolysis temperature range of rice husk, and the activation energy of pyrolysis was between 67.858 kJ/mol and 80.394 kJ/mol; during the pyrolysis of rice husk under CO2/N2 atmosphere, the addition of CO2 gas could promote the positive conversion of CO2, which was more inclined to produce C2H6 and C3H6; meanwhile, it could promote the decomposition of some macromolecular biological compounds.
稻壳Var在CO2/N2气氛下的热解特性研究
主要采用热重差热分析法研究CO2/N2气氛下稻壳的热解特性,其中采用Coats Redfern法分析CO2/N2气氛下稻壳的热解动力学,采用两段固定床热解反应器研究CO2/N2气氛下稻壳的热解产物。结果表明:拟合曲线在稻壳主要热解温度范围内具有较好的相关性,热解活化能在67.858 ~ 80.394 kJ/mol之间;在CO2/N2气氛下稻壳热解过程中,CO2气体的加入促进了CO2的正向转化,更倾向于生成C2H6和C3H6;同时,它还能促进某些大分子生物化合物的分解。
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